Yes. If you had the job offer from the new job in hand when you quit your old job, you can.
Do not be overly alarmed if your old job objects to your claim your claim by filing for Relief From Charges (if it is chargeable for your benefits as your sole or primary Base Year employer).
However, if this does occur, you may need to go to an Unemployment Hearing before a Referee. At that Hearing, you will have to prove that you had job offer in hand on the day you resigned. If you are able to prove that, your right to benefits will be unaffected, even if your former employer is not charged for them (there exists a fund of surplus benefits out of which you will be paid for situations like this).
Here is a Video addressing quit cases under Pennsylvania Unemployment law:
Philadelphia Are Employment Attorney Representing Employees
|Fighting for Pennsylvania's Workforce Since 1991|
John A. Gallagher is an employment lawyer who represents employees in Pennsylvania.
John typically represents employees who need an employment lawyer in Philadelphia County, Chester County, Delaware County, Bucks County, Berks County, Lancaster County and Montgomery County.
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